Odoo v8 Documentation

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There is a very good collection by Stephen Mack!

Official odoo v8 docs (included with github source code)
Official future odoo v8 docs † (Developer tutorial/reference/api & Designer tutorial) (ReadTheDocs Format)
Odoo v8 database scheme (Thanks go to Borut Jures for his work)
Odoo's new v8 API guidelines (From OpenDays 2014)
OpenERP v8 book (Community written)
Official odoo how-to docs (Community written, odoo approved)

OpenERP Version 7

Official OpenERP v7 docs
Official OpenERP Web Developers Documentation v7
Official OpenERP Technical Memento v0.7.4 (French Version)
OpenERP v7 docs (Written by odoo silver partner - erpweb)

† Odoo sponsered developer tutorial/reference/api & designer tutorial for odoo v8 are currently being written and they should start becomming available in September/October 2014. The above link is to the live documents as they are being written. Follow and comment on GitHub. Thanks.